User:Graeme Bartlett/fluoropnictides

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The fluoropnictides are mixed anion compounds that contain both fluoride and phosphide, arsenide, antimonide or bismuthide anions (F− and N3−, P3−, As3− Sb3−, Bi3−).

Many of these are semiconductors. Those that contain iron may be ferromagnetic. Research into these compounds is motivated by the existence of the structurally simlar oxyarsenide superconductors.

List[edit]

Phosphorus[edit]

name formula ratio system space group unit cell volume density band gap properties references
BaFMgP 1:1 tetragonal P4/nmm a=4.3097 c=9.5032 band gap 2 eV [1]
BaMnPF 1:1 [2]
SrZnPF 1:1 [2]
BaZnPF 1:1 tetragonal P4/nmm semiconductor [2]

Arsenic[edit]

Many arsenic fluorides crystallize in the tetragonal system, and those containing iron are superconductors.

name formula ratio system space group unit cell volume density band gap properties references
CaFeAsF 1:1 tetragonal P4/nmm a=3.8784 c=8.5926 superconductor Tc = 29 K [3]
CaFe0.9Co0.1AsF 1:1 tetragonal P4/nmm a=3.8806 c=8.5517 superconductor Tc 22K [3]
KCa2Fe4As4F2 a=3.8684 c=31.007
 463.99 superconductor Tc 33 K [4][5]
RbCa2Fe4As4F2 a=3.8716 c=31.667 474.66 Tc 30.5K [6]
CsCa2Fe4As4F2 a=3.8807 c=32.363 487.38 Tc 28.2K [6]
SrFeAsF tetragonal a=4.004 c=8.971 superconductor > 1GPa [7]
Sr1-xLaxFeAsF superconductor x=0.14 Tc=29.5 K [8]
LaFeAsO1−xFx superconductor: for x = 0.14 Tc=40 K at 3 GPa [9]
Ca0.5Pr0.5FeAsF Tc ~52K [10]
Sr0.5Sm0.5FeAsF 1:1 superconductor Tc 56K [2]
Sr0.5Nd0.5FeAsF Tc 49K [11]
Ca0.4Nd0.6FeAsF 1:1 [2]
Ca0.5Sm0.5FeAsF Superconductors Tc 54.2 K [12]
EuFeAsF [13]
EuAsFeO0.85F0.15 Tc 11.3 K [14]
EuMnAsF [15]
EuFeAsF [15]
EuZnAsF [15]
SmFeAsF tetragonal P4/nmm a = 3.9399 c = 8.5034 Tc 56K [16]
SmCoAsF tetragonal P4/nmm a=3.9555 c=8.2462 Z=2 129.023 black; ferromagnetic < 70K [17]
BaFMgAs tetragonal P4/nmm a=4.3855 c=9.5918 [1]
BaMnAsF 1:1 tetragonal P4/nmm 0.73 semiconductor [2]
BaZnAsF 1:1 tetragonal P4/nmm a = 4.2380 c = 9.5284 [18]
(Ba,K)F(Zn,Mn)As 1:1 tetragonal P4/nmm [18]

Antimony[edit]

name formula ratio mw system space group unit cell volume density band gap properties references
BaFMgSb tetragonal P4/nmm a=4.5733 c=9.8184 [1]
BaZnSbF 1:1 [2]
BaCdSbF 1:1 [2]
BaMnSbF 1:1 333.03 tetragonal P4/nmm a=4.4682 c=9.817 196.00 5.643 0.48 semiconductor [2]

Bismuth[edit]

name formula ratio mw system space group unit cell volume density band gap properties references
BaFMgBi tetragonal P4/nmm a=4.6359 c=9.8599 band gap 1 eV [1]
BaMnBiF

1:1

420.26

tetragonal

P4/nmm

a=4.520 c=9.875

201.7

6.918

0.003

semiconductor

[2]

Artificial[edit]

References[edit]

  1. ^ a b c d Plokhikh, Igor V.; Kuznetsov, Alexey N.; Charkin, Dmitri O.; Shevelkov, Andrei V.; Pfitzner, Arno (2019-03-04). "Layered Compounds BaFMgPn (Pn = P, As, Sb, and Bi), Transition-Metal-Free Representatives of the 1111 Structure Type". Inorganic Chemistry. 58 (5): 3435–3443. doi:10.1021/acs.inorgchem.8b03554. ISSN 0020-1669. PMID 30788958.
  2. ^ a b c d e f g h i j Saparov, Bayrammurad; Singh, David J.; Garlea, Vasile O.; Sefat, Athena S. (2013-07-08). "Crystal, magnetic and electronic structures and properties of new BaMn Pn F ( Pn = As, Sb, Bi)". Scientific Reports. 3 (1): 2154. arXiv:1306.5182. Bibcode:2013NatSR...3E2154S. doi:10.1038/srep02154. ISSN 2045-2322. PMC 6504822. PMID 23831607.
  3. ^ a b Matsuishi, Satoru; Inoue, Yasunori; Nomura, Takatoshi; Yanagi, Hiroshi; Hirano, Masahiro; Hosono, Hideo (2008-11-05). "Superconductivity Induced by Co-Doping in Quaternary Fluoroarsenide CaFeAsF". Journal of the American Chemical Society. 130 (44): 14428–14429. doi:10.1021/ja806357j. ISSN 0002-7863. PMID 18842039.
  4. ^ Wang, Zhi-Cheng; He, Chao-Yang; Tang, Zhang-Tu; Wu, Si-Qi; Cao, Guang-Han (January 2017). "Crystal Structure and Superconductivity at about 30 K in $A$Ca$_2$Fe$_4$As$_4$F$_2$ ($A$ = Rb, Cs)". Science China Materials. 60 (1): 83–89. arXiv:1704.01051. doi:10.1007/s40843-016-5150-x. ISSN 2095-8226.
  5. ^ Wang, Zhi-Cheng; He, Chao-Yang; Wu, Si-Qi; Tang, Zhang-Tu; Liu, Yi; Ablimit, Abduweli; Feng, Chun-Mu; Cao, Guang-Han (2016-06-29). "Superconductivity in KCa 2 Fe 4 As 4 F 2 with Separate Double Fe 2 As 2 Layers". Journal of the American Chemical Society. 138 (25): 7856–7859. arXiv:1607.01611. doi:10.1021/jacs.6b04538. ISSN 0002-7863. PMID 27321364.
  6. ^ a b Wang, Zhi-Cheng; He, Chao-Yang; Tang, Zhang-Tu; Wu, Si-Qi; Cao, Guang-Han (January 2017). "Crystal Structure and Superconductivity at about 30 K in $A$Ca$_2$Fe$_4$As$_4$F$_2$ ($A$ = Rb, Cs)". Science China Materials. 60 (1): 83–89. arXiv:1704.01051. doi:10.1007/s40843-016-5150-x. ISSN 2095-8226.
  7. ^ Han, Fei; Zhu, Xiyu; Mu, Gang; Cheng, Peng; Wen, Hai-Hu (2008-11-11). "SrFeAsF as a parent compound for iron pnictide superconductors". Physical Review B. 78 (18): 180503. arXiv:0810.2475. Bibcode:2008PhRvB..78r0503H. doi:10.1103/PhysRevB.78.180503. ISSN 1098-0121.
  8. ^ Zhu, Xiyu; Han, Fei; Cheng, Peng; Mu, Gang; Shen, Bing; Fang, Lei; Wen, Hai-Hu (January 2009). "Superconductivity in fluoride-arsenide Sr 1-x La x FeAsF compounds". EPL (Europhysics Letters). 85 (1): 17011. arXiv:0810.2531. doi:10.1209/0295-5075/85/17011. ISSN 0295-5075.
  9. ^ Fujiwara, Naoki; Nakano, Tatsuya; Tatsumi, Kenichiro; Okada, Hironari; Takahashi, Hiroki; Kamihara, Yoichi; Hirano, Masahiro; Hosono, Hideo (2010-01-01). "Superconductivity of LaFeAsO 1− x F x under high pressure studied using NMR". Journal of Physics: Conference Series. 200 (1): 012042. doi:10.1088/1742-6596/200/1/012042. ISSN 1742-6596.
  10. ^ Sasmal, Kalyan; Hadjiev, Viktor; Chu, C. W. (Paul) (2016-01-01). "High-Tc Superconductivity and Raman Scattering Study of the phonon properties of electron doped (transition metal, rare-earth) - Oxygen-Free CaFeAsF and compared with RFeAsO system". Aps March Meeting Abstracts. 2016: T1.199. Bibcode:2016APS..MAR.T1199S.
  11. ^ Suganuma, Ryosuke; Watanabe, Tadataka; Takase, Kouichi; Takano, Yoshiki (April 2011). "Superconductivity in Fluorine-Arsenide Sr1-xNdxFeAsF". Solid State Phenomena. 170: 87–91. doi:10.4028/www.scientific.net/SSP.170.87. ISSN 1662-9779.
  12. ^ Pervakov, K. S.; Kulikova, L. F.; Tsvetkov, A. Yu.; Vlasenko, V. A. (August 2022). "Novel Iron-Based Superconductor Ca0.5Sm0.5FeAsF". Bulletin of the Lebedev Physics Institute. 49 (8): 242–246. Bibcode:2022BLPI...49..242P. doi:10.3103/S106833562208005X. ISSN 1068-3356.
  13. ^ Zhu, Xiyu; Han, Fei; Cheng, Peng; Mu, Gang; Shen, Bing; Fang, Lei; Wen, Hai-Hu (January 2009). "Superconductivity in fluoride-arsenide Sr 1-x La x FeAsF compounds". EPL (Europhysics Letters). 85 (1): 17011. arXiv:0810.2531. doi:10.1209/0295-5075/85/17011. ISSN 0295-5075.
  14. ^ Dmitriev, V. M.; Khlybov, E. P.; Kondrashov, D. S.; Terekhov, A. V.; Rybaltchenko, L. F.; Khristenko, E. V.; Ishchenko, L. A.; Kostyleva, I. E.; Zaleski, A. J. (2011-04-01). "Andreev reflection spectroscopy of the new Fe-based superconductor EuAsFeO0.85F0.15: Evidence of strong anisotropy in the order parameter". Low Temperature Physics. 37 (4): 280–286. arXiv:1012.2010. doi:10.1063/1.3590753. ISSN 1063-777X.
  15. ^ a b c Plokhikh, Igor V.; Tsirlin, Alexander A.; Khalyavin, Dmitry D.; Fischer, Henry E.; Shevelkov, Andrei V.; Pfitzner, Arno (2023). "Effect of antifluorite layer on the magnetic order in Eu-based 1111 compounds, EuTAsF (T = Zn, Mn, and Fe)". Physical Chemistry Chemical Physics. 25 (6): 4862–4871. arXiv:2212.10312. Bibcode:2023PCCP...25.4862P. doi:10.1039/D2CP04863A. ISSN 1463-9076. PMID 36692371.
  16. ^ Lin, Dan; Xu, Han-Shu; Luo, Jingjing; Huang, Haoliang; Lu, Yalin; Tang, Kaibin (2019-11-18). "A Self-Doped Oxygen-Free High-Critical-Temperature (High- T c ) Superconductor: SmFFeAs". Inorganic Chemistry. 58 (22): 15401–15409. doi:10.1021/acs.inorgchem.9b02464. ISSN 0020-1669. PMID 31674179.
  17. ^ Lin, Dan; Luo, Qinxin; Zheng, Hui; Tang, Lulu; Zhan, Wenqi; Tang, Kaibin (2020). "A new oxygen-free cobalt-based compound SmCoAsF with multiple magnetic transitions". CrystEngComm. 22 (25): 4268–4274. doi:10.1039/D0CE00448K. ISSN 1466-8033.
  18. ^ a b Chen, Bijuan; Deng, Zheng; Li, Wenmin; Gao, Moran; Liu, Qingqing; Gu, C. Z.; Hu, F. X.; Shen, B. G.; Frandsen, Benjamin; Cheung, Sky; Lian, Liu (2016-11-22). "New Fluoride-arsenide Diluted Magnetic Semiconductor (Ba,K)F(Zn,Mn)As with Independent Spin and Charge Doping". Scientific Reports. 6 (1): 36578. Bibcode:2016NatSR...636578C. doi:10.1038/srep36578. ISSN 2045-2322. PMC 5118802. PMID 27874044.
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